Oligomerization of Unsaturated Compounds in the Presence of Amorphous Mesoporous Aluminosilicates

Autor:	N. G. Grigor’eva, B. I. Kutepov, D. V. Serebrennikov, M. R. Agliullin, S. V. Bubennov
Rok vydání:	2019
Předmět:	010405 organic chemistry General Chemical Engineering Energy Engineering and Power Technology General Chemistry respiratory system musculoskeletal system 010402 general chemistry 01 natural sciences respiratory tract diseases 0104 chemical sciences Amorphous solid chemistry.chemical_compound Fuel Technology chemistry Geochemistry and Petrology Cyclooctene Aluminosilicate Polymer chemistry Molar mass distribution Zeolite Mesoporous material Selectivity Norbornene
Zdroj:	Petroleum Chemistry. 59:682-690
ISSN:	1555-6239 0965-5441
DOI:	10.1134/s096554411907003x
Popis:	High activity and selectivity of the samples of ASM amorphous mesoporous aluminosilicates in the synthesis of practically important oligomers of various unsaturated compounds (C5–C16 linear α-olefins, cyclooctene, norbornene, and α-methylstyrene) is found. The oligomerization products obtained in the presence of ASM have a broader molecular weight distribution in comparison with the oligomers synthesized over the H-Beta zeolite. The mesoporous structure of the ASM aluminosilicate provides the preparation of dimers of cyclooctene with high selectivity without cycle opening.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::aa977312962d5859c150a51d63f36eda https://doi.org/10.1134/s096554411907003x Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
Nepřihlášeným uživatelům se plný text nezobrazuje	K zobrazení výsledku je třeba se přihlásit.