Reactions of coordinated molecules. 35. Carbon-carbon bond formation between adjacent acyl ligands in (metalla-.beta.-diketonato)difluoroboron complexes of iron, manganese, and rhenium

Autor:	P. Galen Lenhert, K. Srinivasan, Charles M. Lukehart
Rok vydání:	1984
Předmět:	Diketone chemistry.chemical_classification chemistry.chemical_element General Chemistry Crystal structure Manganese Metallacycle Rhenium Biochemistry Medicinal chemistry Catalysis Colloid and Surface Chemistry chemistry Carbon–carbon bond X-ray crystallography Molecule
Zdroj:	Journal of the American Chemical Society. 106:124-130
ISSN:	1520-5126 0002-7863
Popis:	Quand les complexes de type L n M(CH 3 CO)(RCO)BF 2 sont traites avec KH, ou la tetramethylpiperidine, un proton est elimine du coordinat acetyl pour donner des complexes η 3 -allyl anioniques de type {L n M[η 3 -CH 2 COCO(R)BF 2 ]} − . Etude RX de PPN{cis-(OC) 4 Mn[η 3 -CH 2 COCO(i-Pr)BF 2 ]}
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::aa8ef038f1f64aafcee539808a96d0e6 https://doi.org/10.1021/ja00313a026 Zobrazit plný text záznamu