Facile Synthesis of Aluminum‐Bridged [3,3,3]Cyclophanes by Hydroalumination

Autor:	Madhat Matar, Alexander Hepp, Andrej Vinogradov, Werner Uhl
Rok vydání:	2007
Předmět:	Inorganic Chemistry chemistry.chemical_compound Chemistry Aluminium Stereochemistry chemistry.chemical_element Lewis acids and bases Benzene Triple bond Medicinal chemistry Adduct Cyclophane
Zdroj:	European Journal of Inorganic Chemistry. 2007:4133-4137
ISSN:	1099-0682 1434-1948
DOI:	10.1002/ejic.200700481
Popis:	The reaction of 1,3,5-tris(3,3-dimethyl-1-butinyl)benzene C6H3(C≡C–CMe3)3 with the dialkylaluminum hydrides HAl(CMe3)2 and HAl(CH2CMe3)2 gave the addition of one Al–H bond to each C–C triple bond (hydroalumination). Spontaneous condensation by the release of the corresponding trialkylaluminum derivatives afforded [3,3,3]cyclophane derivatives 6 and 7 in which three tricoordinate Al atoms are in the bridging positions between two functionalized benzene rings. The aluminum atoms behave as Lewis acids, and treatment with thf yielded adduct 6·3thf. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::aa6bf3e352f01292e932c130b7e9370c https://doi.org/10.1002/ejic.200700481 Zobrazit plný text záznamu Plný text