| Autor: |
AG Williamson, JR Baker, ID Watson |
| Rok vydání: |
1971 |
| Předmět: |
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| Zdroj: |
Australian Journal of Chemistry. 24:2047 |
| ISSN: |
0004-9425 |
| DOI: |
10.1071/ch9712047 |
| Popis: |
The hydrogen bonding between chloroform and di-n-alkyl ethers has been studied over the temperature range -50�C to + 50�C using proton magnetic resonance. The measurements of chemical shift have been interpreted in terms of the formation of a 1 : 1 complex between the chloroform and the ether. Mole fraction association constants in the range 1-5 were found. The enthalpies of formation of the complexes deduced from the temperature coefficients of the equilibrium constants varied from -8 kJ mol-1 to -11.7 kJ mol-1. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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