A Π-Adduct of Chromocene: (η5-C5H5)2Cr(η2-C4F6)

Autor:	Malcolm H. Chisholm, J. E. Bercaw, W. W. Reichert, T. D. Gallagher, F. A. Cotton
Rok vydání:	1977
Předmět:	Inorganic Chemistry chemistry.chemical_compound Paramagnetism Chemistry Hydrocarbon solvents Polymer chemistry Inorganic chemistry Empirical formula Diamagnetism Physical and Theoretical Chemistry Chromocene Adduct
Zdroj:	Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 7:279-289
ISSN:	1532-2440 0094-5714
DOI:	10.1080/00945717708055966
Popis:	Chromocene and hexafluorobut-2-yne react in hydrocarbon solvents at temperatures below -30® to give a green, diamagnetic φ-complex, (η5-C5H5)2Cr(η2-C4F6). At higher temperatures a purple paramagnetic complex, of empirical formula CrC14H10F6, is formed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a9fa853a1a0c266456514086305fa6dd https://doi.org/10.1080/00945717708055966 Zobrazit plný text záznamu