A comparison of laser ablation inductively coupled plasma mass spectrometry, micro X-ray fluorescence spectroscopy, and laser induced breakdown spectroscopy for the discrimination of automotive glass
| Autor: | Sayuri Umpierrez, José R. Almirall, Benjamin E. Naes, Cleon Barnett, Scott Ryland |
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| Rok vydání: | 2008 |
| Předmět: |
Strontium
Chemistry Laser ablation inductively coupled plasma mass spectrometry Analytical chemistry chemistry.chemical_element Laser humanities Atomic and Molecular Physics and Optics Fluorescence spectroscopy Analytical Chemistry law.invention La icp ms law Micro-X-ray fluorescence Laser-induced breakdown spectroscopy Spectroscopy Instrumentation |
| Zdroj: | Spectrochimica Acta Part B: Atomic Spectroscopy. 63:1145-1150 |
| ISSN: | 0584-8547 |
| DOI: | 10.1016/j.sab.2008.07.005 |
| Popis: | Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), micro X-ray fluorescence spectroscopy (μXRF), and laser induced breakdown spectroscopy (LIBS) are compared in terms of discrimination power for a glass sample set consisting of 41 fragments. Excellent discrimination results (> 99% discrimination) were obtained for each of the methods. In addition, all three analytical methods produced very similar discrimination results in terms of the number of pairs found to be indistinguishable. The small number of indistinguishable pairs that were identified all originated from the same vehicle. The results also show a strong correlation between the data generated from the use of µXRF and LA-ICP-MS, when comparing µXRF strontium intensities to LA-ICP-MS strontium concentrations. A 266 nm laser was utilized for all LIBS analyses, which provided excellent precision ( |
| Databáze: | OpenAIRE |
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