Thermodynamics of trichlorethanal, its polymerization in bulk and in polytrichlorethanal within the 0–330 K range

Autor:	B.V. Lebedev, V.G. Vasilev
Rok vydání:	1991
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Monomer chemistry Bulk polymerization Polymerization General Engineering Thermodynamics Polymer Atmospheric temperature range Adiabatic process Heat capacity Calorimeter
Zdroj:	Polymer Science U.S.S.R.. 33:735-742
ISSN:	0032-3950
DOI:	10.1016/0032-3950(91)90131-9
Popis:	The thermodynamic parameters for the bulk polymerization of trichlorethanal for the range 0–330 K are determined from the results of calorimetric studies. The heat capacity at constant pressure Cp0 of the monomer and polymer for the temperature range 11–330 K are studied in an adiabatic vacuum calorimeter, and the temperatures and enthalpies of the physical changes are determined. Polytrichlorethanal is studied over the 220–420 K range by the DTA method. The thermodynamic functions for the substances studied are calculated for the 0–330 K range from data obtained.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a9cd7942d8bd974aaf7f07f867a55c24 https://doi.org/10.1016/0032-3950(91)90131-9 Zobrazit plný text záznamu