The Staudinger reaction of imines derived from 7-oxanorbornenone: formation of spiranic oxazinone versus β-lactam rings

Autor:	Aurelio G. Csaky, Odón Arjona, M. Carmen Murcia, Joaquín Plumet
Rok vydání:	2002
Předmět:	chemistry.chemical_compound chemistry Organic Chemistry Drug Discovery polycyclic compounds Lactam Organic chemistry Staudinger reaction Biochemistry
Zdroj:	Tetrahedron Letters. 43:6405-6408
ISSN:	0040-4039
Popis:	The Staudinger reaction of imines derived from 7-oxanorbornenone with 2-alkoxyacetyl chlorides afforded spiro-β-lactams albeit with an unexpected stereochemistry. This was not the case with arylacetic acid chlorides, which gave rise to spiranic oxazinone rings as well as the expected β-lactams.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a9c5a10e4d3464d8c92125805469c9e6 https://doi.org/10.1016/s0040-4039(02)01375-8 Zobrazit plný text záznamu Full Text from ScienceDirect