Chemical, Plasma Chemical, and Photochemical Methods for Preparing Digermane
| Autor: | N. V. Karpova, G. M. Mochalov, S. S. Suvorov, A. V. Barysheva |
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| Rok vydání: | 2020 |
| Předmět: |
General Chemical Engineering
Condensation 02 engineering and technology General Chemistry Plasma Activation energy 010402 general chemistry 021001 nanoscience & nanotechnology Photochemistry Kinetic energy 01 natural sciences 0104 chemical sciences chemistry.chemical_compound chemistry Germane Yield (chemistry) Digermane 0210 nano-technology Corona discharge |
| Zdroj: | Russian Journal of Applied Chemistry. 93:1681-1687 |
| ISSN: | 1608-3296 1070-4272 |
| Popis: | Photochemical, chemical, and plasma chemical procedures for preparing digermane were studied experimentally. The plasma chemical procedure in corona discharge is the most promising. The kinetic curves of the digermane synthesis in corona discharge were obtained experimentally, and the activation energy was calculated. The removal of digermane from the reaction zone using a flow-through reactor with partial condensation of digermane in the first step and germane in the second step allows the digermane yield to be increased to 96%. |
| Databáze: | OpenAIRE |
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