Broad-range spin-crossover modulation in guest-responsive 2D Hofmann-type coordination polymers
Autor: | Alejandro Orellana-Silla, Rubén Turo-Cortés, Víctor Rubio-Giménez, Carlos Bartual-Murgui, Rob Ameloot, Carlos Martí-Gastaldo, M. Carmen Muñoz, José Antonio Real |
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Rok vydání: | 2023 |
Předmět: | |
Zdroj: | Inorganic Chemistry Frontiers. 10:600-611 |
ISSN: | 2052-1553 |
DOI: | 10.1039/d2qi02252d |
Popis: | Replacement of the function X = −NH2 with −OH in the 5X-pyrimidine axial ligand of the 2D Hofmann polymer {FeII(Lax)2[MII(CN)4]}n (MII = Pt, Pd) enhances guest uptake and enables a wide range of one, two and three stepped spin crossover behaviours. |
Databáze: | OpenAIRE |
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