A Comparative Study of State and Reactivity of Copper Ions Embedded in Various Molecular Sieve Materials

Autor:	F. Vogt, W. Mörke, I. Achkar, K.‐P. Wendlandt
Rok vydání:	1991
Předmět:	Mole ratio law Chemistry Covalent bond Inorganic chemistry chemistry.chemical_element Reactivity (chemistry) Thermal treatment Electron paramagnetic resonance Molecular sieve Copper Ion law.invention
DOI:	10.1016/s0167-2991(08)61573-6
Popis:	The coordination, localization, stabilization and reduction of copper ions embedded in various zeolitic and oxidic materials were studied using EPR and TPR. Coordination polyhedra and kind of ligands in the copper complexes after thermal treatment at 250 and 500°C has been evaluated and their relation to TPR results is shown. The covalent bond character of the copper-matrix interaction increases with increasing SiO 2 /Al 2 O 3 mole ratio in zeolites.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a9402b6d2213f7f5c32c2c7f558185f0 https://doi.org/10.1016/s0167-2991(08)61573-6 Zobrazit plný text záznamu