Thermal investigation on crude oil oxidation kinetics through TG/DTG and DTA tests
| Autor: | Min Liu, Wanfen Pu, Xian-Ping Ma, Ji-Hui Ni, Zhang Jie, Peng-Gang Liu |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Work (thermodynamics)
Light crude oil Chemistry General Chemical Engineering Kinetics Analytical chemistry Energy Engineering and Power Technology 02 engineering and technology General Chemistry Geotechnical Engineering and Engineering Geology Kinetic energy Crude oil 01 natural sciences 010406 physical chemistry 0104 chemical sciences Fuel Technology 020401 chemical engineering Thermal 0204 chemical engineering |
| Zdroj: | Petroleum Science and Technology. 34:685-692 |
| ISSN: | 1532-2459 1091-6466 |
| DOI: | 10.1080/10916466.2016.1156130 |
| Popis: | In this nonisothermal research, the thermal behavior and oxidation kinetics of crude oils were investigated through TG/DTG and DTA tests at three heating rates. The resulting curves exhibit three integrated reactions of distinct oxidation mechanisms (LTO, FD, and HTO) sequentially in overlapped temperature intervals as reaction progresses, the behaviors of that are affected greatly by heating rate. Because of the larger amounts of heavy components and higher availability of deposited fuel, heavy oil exhibits more excellent heat release capability but higher kinetic parameters than light oil, especially in HTO region. Due to the insufficient parameters calculation based on a single kinetic method, other formulated models would be introduced for comparative analysis in the next work to upgrade kinetic research. |
| Databáze: | OpenAIRE |
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