The relationship between photophysical properties and aromaticity/antiaromaticity of various expanded porphyrins — a Hans Fischer Career Award paper

Autor:	Dongho Kim, Jin Seok Kim, Gakhyun Kim
Rok vydání:	2020
Předmět:	Computational chemistry Chemistry Möbius aromaticity Aromaticity Reactivity (chemistry) General Chemistry Antiaromaticity
Zdroj:	Journal of Porphyrins and Phthalocyanines. 24:1278-1299
ISSN:	1099-1409 1088-4246
Popis:	Understanding aromaticity is crucial for predicting the molecular properties and reactivity of cyclic [Formula: see text]-conjugated systems. In this review, representative reports on the evaluation of aromaticity via spectroscopic methods in various expanded porphyrin systems are presented. The relationship between the photophysical properties and distinct aromatic characteristics in Hückel aromatic compounds was revealed through notable spectroscopic features exhibited by aromatic expanded porphyrins. Furthermore, modulating the molecular conformation and chemical environment enabled us to distinguish unique Möbius aromatic molecules successfully. These findings provide insight into the elemental molecular properties and aromaticity in expanded porphyrin systems and their potential real-world applications.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a8d47d799ee65947a2bfba1bffb32a03 https://doi.org/10.1142/s1088424620300074 Zobrazit plný text záznamu