Synthesis and properties of 1,3- and 1,4-{(η5-C6H)Mn(CO)3}2-C5H4: molecular structure of [(μ-η5:η5:η5-C17H15)(CH3)Mn2W(CO)9]

Autor:	Young Keun Chung, June-ho Jung, Soon W. Lee, Jung-A Kim, Taek-Mo Chung
Rok vydání:	1995
Předmět:	Stereochemistry Chemistry Organic Chemistry chemistry.chemical_element Crystal structure Manganese Biochemistry Medicinal chemistry Inorganic Chemistry Cyclopentadienyl complex Yield (chemistry) Materials Chemistry Molecule Physical and Theoretical Chemistry Group 2 organometallic chemistry
Zdroj:	Journal of Organometallic Chemistry. 486:211-216
ISSN:	0022-328X
DOI:	10.1016/0022-328x(94)05046-e
Popis:	( exo -C 5 H 5 - η 5 -C 6 H 6 )Mn(CO) 3 ( 2 ) reacts with (C 6 H 6 )Mn(CO) 3 + to yield 1,3- and 1,4-{( gh 5 -C 6 H 6 )Mn(CO) 3 } 2 -C 5 H 4 )] ( 3 ). ( 3 ) reacts with Fe 2 (CO) 9 to yield [( μ - η 5 : η 5 : η 5 -C 17 H 15 )Mn 2 Fe(CO) 8 ] 2 . 3 reacts with n BuLi to produce a lithiated compound, which reacts with M(CO) 5 Br (MMn, Re), M(CO) 3 (CH 3 CN) 3 (MCr, Mo, W), and FeCl 3 to yield the corresponding organometallic compounds. The molecular structure of [( μ - η 5 : η 5 : η 5 -C 17 H 15 )(CH 3 )Mn 2 W(CO) 9 ] ( 6 (W)) (space group P 2 1 / c ; unit cell parameters a = 11.208(6), b = 19.431(3), c = 12.562(2) A , β = 91.69 (3)°; R = 0.052%, R W = 0.067%) has been determined.
Databáze:	OpenAIRE
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