The identification of the classical donor–acceptor complex H3N–BF3in the gas phase

Autor:	H. E. Warner, A. C. Legon
Rok vydání:	1991
Předmět:	chemistry.chemical_classification Spectrometer Stereochemistry Condensation Isotopomers Adduct chemistry.chemical_compound chemistry Chemical physics Molecular Medicine Molecule Inorganic compound Microwave Boron trifluoride
Zdroj:	J. Chem. Soc., Chem. Commun.. :1397-1399
ISSN:	0022-4936
DOI:	10.1039/c39910001397
Popis:	The J=1 â†� 0 rotational transitions of the four isotopomers H314N11BF3, H314N10BF3, H315N11BF3 and H315N10BF3 of the archetypal donor–acceptor complex formed between ammonia and boron trifluoride have been detected with a pulsed-nozzle, Fourier-transform microwave spectrometer; by using a fast-mixing nozzle, H3NBF3 has been isolated in collisionless expansion before condensation can occur, thereby allowing the first detection of this elusive species in the gas phase.
Databáze:	OpenAIRE
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