Effect of natural zeolite and kaolin as a catalyst in the isothermal-catalytic cracking of real municipal solid waste (MSW) for bio-oil production
Autor: | M. D. Susila, Heri Rustamaji, Indra Mamad Gandidi |
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Rok vydání: | 2018 |
Předmět: |
Olefin fiber
Materials science 0211 other engineering and technologies chemistry.chemical_element 02 engineering and technology 010501 environmental sciences Fluid catalytic cracking 01 natural sciences Catalysis Diesel fuel Chemical engineering chemistry 021108 energy Gasoline Zeolite Pyrolysis Carbon 0105 earth and related environmental sciences |
Zdroj: | IOP Conference Series: Earth and Environmental Science. 160:012018 |
ISSN: | 1755-1315 1755-1307 |
DOI: | 10.1088/1755-1315/160/1/012018 |
Popis: | A real MSW conversion into bio-oil by pyrolysis method had been investigated. The pyrolysis experiment was carried out in an isothermal fixed bed reactor at 400 °C for 60 min. Natural activated zeolite and kaolin catalysts were employed in this process with catalyst-MSW at ratio of 0.5 w/w. Influence of activated catalyst to pyrolysis productivity and bio-oil properties were studied. Comparison between zeolite and kaolin catalytic pyrolysis was examined and bio-oil products were analyzed by GC-MS. The yields of liquid fuel or bio-oil were found around 23.6 and 21.4% for kaolin and zeolite catalytic pyrolysis, respectively. The carbon range distribution in bio-oil were 65.38% of gasoline range (C5-C12) and 33.49% of diesel range (C13-C20) for activated kaolin catalytic cracking. Activated zeolite had 51.62% of gasoline range (C5-C12) and 48.37% of diesel range (C13-C20). The results showed that both of bio-oil products mostly contained paraffin and olefin. The use of kaolin as catalyst was better than zeolite in converting the real MSW into bio-oil. |
Databáze: | OpenAIRE |
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