Photodimerization of phenanthrene-9-carbonitrile and methyl phenanthrene-9-carboxylate

Autor:	Eric L. Burch, Frederick D. Lewis, Steven V. Barancyk
Rok vydání:	1992
Předmět:	Nitrile Chemistry Dimer General Engineering Quantum yield Phenanthrene Excimer Photochemistry Medicinal chemistry chemistry.chemical_compound Reaction rate constant Carboxylate Physical and Theoretical Chemistry Dichloromethane
Zdroj:	The Journal of Physical Chemistry. 96:2548-2553
ISSN:	1541-5740 0022-3654
DOI:	10.1021/j100185a029
Popis:	The fluorescence self-quenching and photodimerization of three phenanthrene derivatives have been investigated. Methyl phenanthrene-9-carboxylate undergoes self-quenching with a rate constant of 1.2×10 9 M -1 s -1 in dichloromethane to form a weakly bound, nonfluorescent excimer from which the syn head-to-tail dimer is formed efficiently
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a8871e16f9eebe04786b388d5c07e3b0 https://doi.org/10.1021/j100185a029 Zobrazit plný text záznamu