A 3D Cd(II)-organic coordination polymer demonstrating selective sensing of Zn2+ ion and nitrobenzene
| Autor: | Zheng-Bo Han, Na Wei, Shuang Zhang, Rong-Xia Zuo |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Quenching (fluorescence)
010405 organic chemistry Coordination polymer Supramolecular chemistry Infrared spectroscopy 010402 general chemistry 01 natural sciences 0104 chemical sciences Inorganic Chemistry Nitrobenzene chemistry.chemical_compound Crystallography chemistry Materials Chemistry Organic chemistry Physical and Theoretical Chemistry Luminescence Single crystal Powder diffraction |
| Zdroj: | Inorganica Chimica Acta. 453:305-309 |
| ISSN: | 0020-1693 |
| DOI: | 10.1016/j.ica.2016.08.036 |
| Popis: | Cd(II)-organic coordination polymer with the formula [Cd 3 (btdc) 3 (DMF) 2 (EtOH) 2 ]·2EtOH·2H 2 O were solvothermally synthesized by treating Cd(II) nitrates with 2,2′-bithiophene-5,5′-dicarboxylic acid (H 2 btdc) and characterized by single crystal X-ray diffraction, elemental analysis, thermogravimetric analyses, IR spectroscopy and X-ray powder diffraction. Single-crystal X-ray diffraction studies indicate that the Cd(II) complex exhibits a 3D supramolecular framework, in which trinuclear Cd(II) clusters are connected by btdc ligands to form a 2D (4, 4) layer. Furthermore, the 2D (4, 4) layers stacked via AA mode. This complex displays strong fluorescent emission both in the solid state and in methanol suspension at room temperature, which can act as the fluorescent probe for selectively detecting Zn 2+ ions and nitrobenzene through luminescence enhancing and quenching, respectively. |
| Databáze: | OpenAIRE |
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