Stepwise ionization of hydroquinone vapor by monochromatic radiation

Autor:	A. G. Feofilov, V. I. Kleimenov, M. E. Akopyan
Rok vydání:	2000
Předmět:	chemistry.chemical_compound Reaction rate constant Hydroquinone Chemistry Ionization Analytical chemistry Photoionization Physical and Theoretical Chemistry Spectroscopy Dissociation (chemistry) Ion Atmospheric-pressure laser ionization
Zdroj:	High Energy Chemistry. 34:107-111
ISSN:	1608-3148 0018-1439
Popis:	Processes of stepwise ionization of hydroquinone vapor by radiation in the range 315–275 nm were studied using photoionization spectroscopy techniques. The two-step ionization process yielding molecular ions was found to prevail at a laser power density up to ∼107 W/cm2. As the radiation intensity increases, the progressively stronger and deeper degradation takes place via dissociation of the molecular and, probably, fragment ions due to absorption of at least one additional photon. The slow process of the formation of C5H6O0 ions at an effective rate constant of the order of 106 s−1 was observed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a87b457ed7cda81ea293794a06c8bf46 https://doi.org/10.1007/bf02761838 Zobrazit plný text záznamu Full text from SpringerLink