ChemInform Abstract: Synthesis of Styryl Tetrahydrofurans and Tetrahydropyrans via Addition of Radicals to Unsaturated Sulfimides
| Autor: | Stuart M. Rooke, Tim J. Sparey, Paul C. Taylor, Andrew J. Clark |
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| Rok vydání: | 2010 |
| Předmět: | |
| Zdroj: | ChemInform. 27 |
| ISSN: | 0931-7597 |
| Popis: | The addition of tetrahydrofuranyl or tetrahydropyranyl radicals to (E)-styryl sulfimide derivatives furnishes the corresponding (E)-styryl tetrahydrofurans or tetrahydropyrans respectively. The corresponding radical reactions with (Z)-styryl sulfimides gives rise to a mixture of (E) and (Z) isomers, this is in contrast to the Et 3 B mediated reaction, which is stereoselective. |
| Databáze: | OpenAIRE |
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