A comparison of the reaction of S2 with metallic copper, Cu2O and Cu/ZnO: electronic properties and reactivity of copper
| Autor: | José A. Rodriguez, Sanjay Chaturvedi, Mark Kuhn |
|---|---|
| Rok vydání: | 1998 |
| Předmět: |
Copper oxide
Inorganic chemistry Ab initio chemistry.chemical_element Surfaces and Interfaces Zinc Condensed Matter Physics Copper Surfaces Coatings and Films Metal chemistry.chemical_compound chemistry X-ray photoelectron spectroscopy Chemisorption visual_art Materials Chemistry visual_art.visual_art_medium Reactivity (chemistry) |
| Zdroj: | Surface Science. 415:L1065-L1073 |
| ISSN: | 0039-6028 |
| DOI: | 10.1016/s0039-6028(98)00626-8 |
| Popis: | The adsorption of S2 on polycrystalline copper, Cu2O and Cu/ZnO surfaces has been examined by using synchrotron-based photoemission plus INDO/S and ab initio self-consistent-field calculations. S2 mainly interacts with the metal centers of Cu/ZnO, Cu2O and ZnO. The chemical affinity of these systems for sulfur increases following the sequence: ZnO |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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