Synthetic applications of furan Diels-Alder chemistry

Autor: Albert Padwa, C. Oliver Kappe, S. Shaun Murphree
Rok vydání: 1997
Předmět:
Zdroj: Tetrahedron. 53:14179-14233
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(97)00747-3
Popis: 3. Introduction Bimolecular Diels-Alder Reactions of Furans 2.1. Scope and limitations 2.1.1. Alkenes 2.1.2. Alkynes 2.1.3. Allenes 2.2. Reactive g-bonds 2.3. Catalysts and high pressure 2.4. Asymmetric Diels-Alder reactions 2.5. Total synthesis Intramolecular Diels-Alder Reactions of Furans 3.1. Scope and limitations 3.1.1. Nature of the diene 3.1.1.1. Fused furans 3.1.1.2. Vinyl furans 3.1.2. Nature of the dienophile 3.1.2.1. Alkenes 3.1.2.2. Alkynes 3.1.2.3. Ailenes 3.1.2.4. Benzynes 3.2. Mechanistic considerations 3.2.1. Substituent/structural effects 3.2.2 Catalysts 3.2.3. High-pressure reactions 3.3. Applications 3.3.1. Methodology 3.3.2. Asymmetric synthesis 3.3.3 Synthetic targets
Databáze: OpenAIRE