Comments on 'Solubility modelling and solvent effect on solid-liquid equilibrium of 2,2-bis(hydroxymethyl)butyric acid at different temperatures'
| Autor: | William E. Acree, Priya Tirumala, Jennifer Huang |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
Thermodynamics
02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Atomic and Molecular Physics and Optics 0104 chemical sciences Electronic Optical and Magnetic Materials Butyric acid chemistry.chemical_compound chemistry Materials Chemistry Hydroxymethyl Physical and Theoretical Chemistry Solvent effects Solubility 0210 nano-technology Dissolution Spectroscopy Solid liquid |
| Zdroj: | Journal of Molecular Liquids. 314:113668 |
| ISSN: | 0167-7322 |
| DOI: | 10.1016/j.molliq.2020.113668 |
| Popis: | A polemic is given regarding the mathematical expressions used by Mohdee and coworkers to calculate the thermodynamic properties of dissolution of 2,2-bis(hydroxymethyl)butyric acid in seven organic mono-solvents. The authors' calculated thermodynamic properties based on the Apelblat model are compared to numerical values based on published methods used by other researchers. Errors were also noted in Fig. 6 of the published paper for the calculations pertaining to the the Buchowski-Ksiazcak λh equation. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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