Large-Grained Cu2BaSnS4 Films for Photocathodes
Autor: | Fayun Zhang, Guifu Zou, Juan Xie, Fengang Zheng, Robabeh Bagheri, Qinghua Yi |
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Rok vydání: | 2019 |
Předmět: |
Photocurrent
Electron mobility Materials science Aqueous solution Valence (chemistry) business.industry 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Thermal conduction 01 natural sciences Photocathode 0104 chemical sciences Micron scale Optoelectronics Reversible hydrogen electrode General Materials Science 0210 nano-technology business |
Zdroj: | ACS Applied Materials & Interfaces. 11:33102-33108 |
ISSN: | 1944-8252 1944-8244 |
Popis: | p-Type compounds Cu2BaSnS4 (CBTS) are extremely attractive materials for photocathode applications because of their suitable conduction and valence bands, earth-abundant sources, and environmental friendly nature. Herein, an inexpensive and reproducible aqueous solution approach has been developed to synthesize CBTS films with single-crystalline grains as large as micron scale. Because of the large crystalline grains, the as-grown CBTS films show excellent carrier mobility (1.29 cm2/V·s). Greater than 4 mA·cm-2 photocurrent density has been obtained in a neutral solution for bare Mo/CBTS film photocathodes under 100 mW·cm-2 illumination at 0 V versus reversible hydrogen electrode. |
Databáze: | OpenAIRE |
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