Possible negative‐U properties of the cation vacancy in HgCdTe

Autor: Walter A. Harrison, Donald E. Cooper
Rok vydání: 1990
Předmět:
Zdroj: Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films. 8:1112-1115
ISSN: 1520-8559
0734-2101
Popis: The cation vacancy in HgCdTe is commonly used for p‐type doping, but the energy levels of the vacancy acceptor are not known. We propose that the vacancy is a negative‐U center, with inverted energy levels. Comparison with the vacancy in silicon,which is a well‐characterized negative‐U defect, indicates that the HgCdTe vacancy is likely to be a negative‐U center also. The minority carrier recombination rate involving gap levels of the vacancy will show a quadratic dependence on the vacancy concentration, and the deep levels of a negative‐U vacancy may be particularly suitable as recombination centers due to their location near the middle of the gap.
Databáze: OpenAIRE