Transformation Products of Some 2,6-Diacetoxycyclohexanones

Autor:	Gwk Cavill, DH Solomon
Rok vydání:	1962
Předmět:	Green chemistry chemistry.chemical_compound Reaction mechanism chemistry Biocatalysis Butanol Sodium Ionic liquid Organic chemistry chemistry.chemical_element General Chemistry Catalysis Macromolecule
Zdroj:	Australian Journal of Chemistry. 15:764
ISSN:	0004-9425
DOI:	10.1071/ch9620764
Popis:	The specific transformation of a 2,6-diacetoxycyclohexanone into a cyclohexane-1,2-dione in the presence of acid or base, is described. Reduction of the 2,6-diacetoxy-ketone with sodium in butanol gives a 1,2-diol whose structure corresponds to that of the l,2-dione. The diols are useful intermediates in the synthesis of alkylhexane-1,6-dialdehydes.
Databáze:	OpenAIRE
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