A modified model of diffusion-controlled reactions
| Autor: | B. I. Yakobson, A. I. Burshtein |
|---|---|
| Rok vydání: | 1980 |
| Předmět: |
Chemistry
Organic Chemistry Thermodynamics Biochemistry Connection (mathematics) Inorganic Chemistry Orientation (vector space) Reaction rate Intrusion Solvation shell Computational chemistry Reagent Physics::Atomic and Molecular Clusters Relaxation (physics) Physics::Chemical Physics Physical and Theoretical Chemistry Diffusion (business) |
| Zdroj: | International Journal of Chemical Kinetics. 12:261-270 |
| ISSN: | 1097-4601 0538-8066 |
| DOI: | 10.1002/kin.550120407 |
| Popis: | The treatment used for diffusion-controlled reactions is extended to the case when the final jumplike step of the reagent approach differs essentially from the preceding diffusion. In terms of the model proposed it is possible to take into account, in a simple way, chemical inhomogeneity of the reagents when the in-cage reaction rate depends on the pair state (for example, on the molecular orientation). In this connection the reaction can be controlled either by the reagent intrusion into the solvation shell of the partner, or by the in-cage relaxation. |
| Databáze: | OpenAIRE |
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