New anions as supporting electrolytes for rechargeable lithium batteries
| Autor: | L.A. Dominey, V.R. Koch, M.E. Langmuir, J. L. Goldman |
|---|---|
| Rok vydání: | 1987 |
| Předmět: |
Renewable Energy
Sustainability and the Environment Inorganic chemistry Energy Engineering and Power Technology chemistry.chemical_element Ether Electrolyte Conductivity chemistry.chemical_compound chemistry Lithium Sulfolane Electrical and Electronic Engineering Physical and Theoretical Chemistry Solubility Tetrahydrofuran |
| Zdroj: | Journal of Power Sources. 20:287-291 |
| ISSN: | 0378-7753 |
| DOI: | 10.1016/0378-7753(87)80125-8 |
| Popis: | Each of the two most commonly used salts in ambient-temperature rechargeable lithium batteries has problems involving safety and long-term stability. For example, solutions of LiClO4 in 1,3-dioxolane are shock sensitive while LiAsF 6/ether electrolytes degrade (both thermochemically and electrochemically) with time. Studies have been undertaken on the solubility, conductivity, and stability towards lithium of seven new lithium salts in both tetrahydrofuran (THF) and sulfolane. Of the seven salts, LiTaF6, Li2C2F4(SO3)2 and Li2C4F8 (SO3)2 provide reasonable conductivities and good stability in sulfolane at 70 °C. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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