ADMET copolymerization of divinyltetraethoxydisiloxane with 1,9-decadiene catalyzed by Grubbs’ catalyst

Autor:	Ewa Małecka, Kenneth B. Wagener, Cezary Pietraszuk, A. Cameron Church, Bogdan Marciniec
Rok vydání:	2002
Předmět:	Chemistry Process Chemistry and Technology Homogeneous catalysis Carbon-13 NMR Catalysis Grubbs' catalyst chemistry.chemical_compound Polymer chemistry Copolymer Organic chemistry Physical and Theoretical Chemistry Carbene Acyclic diene metathesis
Zdroj:	Journal of Molecular Catalysis A: Chemical. 190:27-31
ISSN:	1381-1169
Popis:	The acyclic diene metathesis (ADMET) copolymerization of divinyltetraethoxydisiloxane with 1,9-decadiene, catalyzed by RuCl 2 (=CHPh)(PCy 3 ) 2 , is the first example of a siloxylene-vinylene-alkenylene copolymer reported in the literature. This copolymer was isolated and characterized by 1 H, and 13 C NMR spectroscopy and GPC analysis (M n = 18000, PDI = 2.9).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a74bdaedd6666693adc87a151dfbe310 https://doi.org/10.1016/s1381-1169(02)00239-x Zobrazit plný text záznamu Full Text from ScienceDirect