Non-innocent ligand reservoirs for reducing or oxidizing equivalents in carbonylrhenium(I) complexes: 1,1′-Bis(diphenylphosphino)ferrocene (dppf) and bis-triazinyl-pyridine (BTP)

Autor:	Travis Blane, Alyssia M. Lilio, Clifford P. Kubiak, Sayak Roy
Rok vydání:	2011
Předmět:	Crystal structure Photochemistry Redox Non-innocent ligand Inorganic Chemistry chemistry.chemical_compound Ferrocene chemistry Polymer chemistry Pyridine Bathochromic shift Materials Chemistry 1 1'-Bis(diphenylphosphino)ferrocene Hypsochromic shift Physical and Theoretical Chemistry
Zdroj:	Inorganica Chimica Acta. 374:134-139
ISSN:	0020-1693
Popis:	Organometallic complexes of Re(I) with ligands having opposite redox properties have been synthesized and structurally characterized. X-ray crystal structures of the complexes show typical fac-ReI(CO)3 coordination to the redox active ligands. Complete electrochemical and spectroelectrochemical studies on the ligands and the metal complexes were performed. The IR-spectroelectrochemical responses were monitored using the fac-Re(CO)3 unit as a probe. The 15–20 cm−1 hypsochromic or bathochromic shift of the νCO bands upon reduction or oxidation is attributed to ligand-centered processes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a7470993067306fc0b0eb48f5289263a https://doi.org/10.1016/j.ica.2011.02.005 Zobrazit plný text záznamu Full Text from ScienceDirect