Kinetics of methyl tert. butyl ether synthesis in gaseous phase

Autor:	Karel Jeřábek, Alena Hejtmánková, Karel Setínek
Rok vydání:	1990
Předmět:	chemistry.chemical_classification Kinetics General Chemistry Primary alcohol Medicinal chemistry Catalysis chemistry.chemical_compound Hydrocarbon chemistry Phase (matter) Organic chemistry Methanol Aliphatic compound Methyl tert-butyl ether
Zdroj:	Collection of Czechoslovak Chemical Communications. 55:1033-1037
ISSN:	1212-6950 0010-0765
Popis:	Kinetics of methyl tert.butyl ether synthesis from methanol and isobutene was measured in gaseous phase at 85 °C and atmospheric pressure on macroreticular ion exchanger catalyst containing strongly acidic functional groups SO3H and on the same catalyst partially neutralized by sodium and iron ions. The form of the best Langmuir-Hinshelwood type kinetic equation suggests absorption of the reactants in the polymer mass causing ìswellingî of it and influencing the accessibility of active sites by the reactants. Neutralization of the catalyst by metal ions suppresses this effect.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a7410ccd5d7d24da54dc2a7255a5c6eb https://doi.org/10.1135/cccc19901033 Zobrazit plný text záznamu