The Electronic Structure of Transition Metal Cluster Complexes with Weak- and Strong-field Ligands

Autor:	Galina P Kostikova, D. V. Korol’kov
Rok vydání:	1985
Předmět:	Ligand field theory Transition metal Metal K-edge Chemistry Chemical physics Cluster (physics) Molecular orbital General Chemistry Electronic structure Atomic physics Valence electron Metal L-edge
Zdroj:	Russian Chemical Reviews. 54:344-360
ISSN:	1468-4837 0036-021X
DOI:	10.1070/rc1985v054n04abeh003040
Popis:	A systematic account and a survey of the results of quantum-chemical and spectroscopic studies of the electronic structure of transition metal cluster complexes are presented. In terms of the theory of canonical molecular orbitals and the theory of weak- and strong-field ligands, the concept of the structure and stability of the clusters taking into account the influence of the ligands and transition metal atoms on the characteristics of the M–M bonds has been formulated. The characteristic features of the delocalisation of the valence electrons of the M atoms in the Mn groups, the intercluster interaction, the density of the M atoms in the clusters, and the effects of cluster formation in the optical and X-ray spectra are discussed. The bibliography includes 137 references.
Databáze:	OpenAIRE
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