Fracture behavior of boehmite-filled polypropylene block copolymer nanocomposites as assessed by the essential work of fracture concept

Autor: László Mészáros, V. M. Khumalo, Ralf Thomann, J. Karger-Kocsis, Tamás Turcsán
Rok vydání: 2014
Předmět:
Zdroj: Journal of Applied Polymer Science. 131
ISSN: 0021-8995
DOI: 10.1002/app.40447
Popis: The essential work of fracture (EWF) method was adapted to determine the fracture toughness of poly(propylene-block- ethylene) (EPBC) based nanocomposites with different amounts (from 0 up to 5 wt %) of synthetic boehmite alumina (BA). The dis- persion of BA in the matrix was studied by transmission and scanning electron microscopies. Agglomerated micronscale along with well dispersed nanoscale BA particles were present in the EPBC matrix. By contrast to the neat EPBC, all nanocomposites failed by unstable necking. Therefore the energy partitioning concept of the EWF was adapted and attention paid to the yielding-related term. Both specific yielding-related essential and nonessential work of fracture parameters increased linearly with the product of the yield stress and elongation at yield derived from static tensile tests. V C 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 40447.
Databáze: OpenAIRE