Preparation of phenanthro[9,10-b]thiophene and properties of its derivatives

Autor:	T. N. Sidorenko, G. A. Terent'eva, V. S. Aksenov
Rok vydání:	1983
Předmět:	Chemistry Decarboxylation Organic Chemistry Halogenation Chloride chemistry.chemical_compound Thionyl chloride Pyridine medicine Thiophene Organic chemistry Saponification medicine.drug Acrylic acid
Zdroj:	Chemistry of Heterocyclic Compounds. 19:161-163
ISSN:	1573-8353 0009-3122
DOI:	10.1007/bf00506425
Popis:	The oxidation of β-(9-phenanthryl)acrylic acid, which was obtained by arylation of acrylic acid with 9-bromophenanthrene, with thionyl chloride in the presence of triethylbenzylammonium chloride leads to the formation of 3-chloro-2-chlorocarbonylphenanthro[9,10-b]thiophene, which, after saponification to give the acid, undergoes simultaneous dehalogenation and decarboxylation under the influence of pyridine with added copper.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a725d2e5e53d6f0d60a02450660cde27 https://doi.org/10.1007/bf00506425 Zobrazit plný text záznamu Full text from SpringerLink