ChemInform Abstract: Acetyl Ketene Aminals in Nenitzescu Reaction

Autor:	O. S. Anisimova, Alexander V. Komkov, E. K. Panisheva, V. A. Dorokhov, L. M. Alekseeva, T. I. Mukhanova, Vladimir G Granik, K. F. Turchin
Rok vydání:	2010
Předmět:	chemistry.chemical_compound Chemistry Organic chemistry Ketene General Medicine Benzoquinone
Zdroj:	ChemInform. 30
ISSN:	1522-2667 0931-7597
Popis:	Nenitzescu reaction of acetyl ketene aminals (N,N-acetals) was investigated. The interaction of 2-acetyl-1-amino-1-anilinoethene with benzoquinone gave 3-acetyl-2-amino-7a-hydroxy-1-phenyl-5,7a-dihydro-1H-indol-5-one, which was then transformed into 3-acetyl-2-amino-6-chloro-5-hydroxy-1-phenylindole. The reaction of benzoquinone with 2-acetyl-1-amino-1-benzoylaminoethene led to the corresponding hydroquinone-adduct which was oxidized to 4-acetylamino-5-(2,5-dihydroxyphenyl)-2-phenyloxazole.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a720539758d6c4f59a461ffd4d46a533 https://doi.org/10.1002/chin.199935046 Zobrazit plný text záznamu Plný text