Intramolecular excimer formation in copolymers of methylmethacrylate and indene

Autor:	M Reyes Vigil, Carmen S. Renamayor, Valentín Moreno‐Montes, M Isabel Esteban
Rok vydání:	2000
Předmět:	Polymers and Plastics Bulk polymerization Chemistry Organic Chemistry Radical polymerization food and beverages chemistry.chemical_compound Monomer Intramolecular force Polymer chemistry Materials Chemistry Proton NMR Copolymer Reactivity (chemistry) Indene
Zdroj:	Polymer International. 49:663-668
ISSN:	1097-0126 0959-8103
DOI:	10.1002/1097-0126(200007)49:7<663::aid-pi428>3.0.co;2-l
Popis:	A set of fifteen samples of indene (IN) with methylmethacrylate (MMA) copolymers was synthesized by free radical polymerization in bulk. Reactivity ratios, mean sequence lengths and distribution-functions of monomeric units indicate the formation of quasirandom copolymers, with a larger tendency to blockiness for MMA units. UV and NMR results are consistent with these observations. No typical signals of strongly interacting aromatic moieties can be identified either in the UV short-wavelength spectra region, or in the 1H NMR aromatic proton region. Photophysical behavior is analysed. © 2000 Society of Chemical Industry
Databáze:	OpenAIRE
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