Thermodynamic properties of binary mixtures: Hexamethylphosphoric triamide (HMPA) with a non-polar liquid at 25�C

Autor:	Masato Fukumori, Katsutoshi Tamura, Yoshikane Kawasaki, Yoshimasa Akagi, Sachio Murakami
Rok vydání:	1994
Předmět:	Heptane Biophysics Analytical chemistry Biochemistry Hexamethylphosphoric Triamide chemistry.chemical_compound chemistry Molecule Isobaric process Organic chemistry Non polar Physical and Theoretical Chemistry Benzene Molecular Biology
Zdroj:	Journal of Solution Chemistry. 23:989-996
ISSN:	1572-8927 0095-9782
DOI:	10.1007/bf00974099
Popis:	Excess isobaric heat capacities C p E , densities π and speeds of sound u of HMPA+heptane and+benzene were measured at 25°C. C p E of both mixtures were positive in the range of small x and negative in the other region. The mixture containing benzene showed higher C p E than the heptane mixture. They both exhibited considerably smaller C V E than C p E . VE was positive for HMPA+heptane and negative for HMPA+benzene. The compressibilities K s E and K p E of both mixtures were negative. In both mixtures, non-random mixing is expected and [(CH3)2N]3PO molecules are inhomogeneously distributed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a712defffa7e17708401591cee6b50c1 https://doi.org/10.1007/bf00974099 Zobrazit plný text záznamu Full text from SpringerLink