Crystal structures, phosphorescent and magnetic properties of novel 1,2-dihydroisoquinoline radicals
| Autor: | Liusong Ni, Guo-Ping Yong |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Pericyclic reaction
010405 organic chemistry Radical Organic Chemistry 010402 general chemistry Photochemistry 01 natural sciences 0104 chemical sciences Analytical Chemistry Inorganic Chemistry Solvent chemistry.chemical_compound chemistry Cascade reaction Cascade Phosphorescence Luminescence Triethylamine Spectroscopy |
| Zdroj: | Journal of Molecular Structure. 1171:614-618 |
| ISSN: | 0022-2860 |
| DOI: | 10.1016/j.molstruc.2018.06.060 |
| Popis: | We unprecedentedly synthesized two novel 1,2-dihydroisoquinoline radicals through cascade ion-type, radical-type and pericyclic reaction mechanisms. This work indicates that from a radical precursor and triethylamine that also was used as a solvent, the 1,2-dihydroisoquinoline framework can be constructed through cascade reactions under high temperature and high pressure condition. Interestingly, 1,2-dihydroisoquinolines not only reveal the phosphorescence, but also the interesting magnetic properties due to their radical nature. The present work provides a promising approach for synthesizing 1,2-dihydroisoquinoline radical materials and a new access to develop cascade reaction for constructing complicated organic compounds by facile high temperature and high pressure synthetic approach. |
| Databáze: | OpenAIRE |
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