Transformations of radicals during photolysis of 2,2-dimethyldihydroquinolines

Autor:	Vladimir A. Kuzmin, Tatiana D. Nekipelova, Ya. N. Malkin
Rok vydání:	1980
Předmět:	chemistry.chemical_compound Ethoxyquin Antioxidant chemistry Electron affinity (data page) Radical medicine.medical_treatment Photodissociation Recombination rate medicine General Chemistry Cleavage (embryo) Photochemistry
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 29:67-72
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00951880
Popis:	1. In solvents with a low electron affinity (hydrocarbons, alcohols) the photolysis of dihydroquinolines leads to cleavage of the N-H bond and to the formation of RN. radicals, which are capable of dimerization, and not to cleavage of the C-N bond and the formation of the o-quinone aldine structure. 2. The low recombination rate of the RN. radicals is one of the reasons for the greater effectiveness of ethoxyquin as antioxidant.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a6e3f143f93a61e424067ac934ca1bc7 https://doi.org/10.1007/bf00951880 Zobrazit plný text záznamu Full text from SpringerLink