Size Effect on the High-Strength and Electrically Conductive Polyolefin/Reduced Graphene Oxide (RGO) Composites
Autor: | Anping Huang, Yu Ma, Wensheng Gao, Yongxiao Bai, Bochao Zhu, Qinjia Chen, Songbo Chen, Jiandong Cao, Junji Jia, Huqiang Chen |
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Rok vydání: | 2018 |
Předmět: |
Materials science
Scanning electron microscope Graphene Oxide Graphite oxide 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Thermal expansion 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials law.invention Polyolefin Linear low-density polyethylene chemistry.chemical_compound General Energy chemistry law Particle size Physical and Theoretical Chemistry Composite material 0210 nano-technology |
Zdroj: | The Journal of Physical Chemistry C. 122:7968-7974 |
ISSN: | 1932-7455 1932-7447 |
DOI: | 10.1021/acs.jpcc.7b12787 |
Popis: | Size-controlled alkylated reduced graphene oxide (M-LTRGO) with a narrow particle size distribution was synthesized in one step via a low-temperature thermal expansion strategy at a large scale. The physicochemical properties of the modified graphite oxide (M-GO) and M-LTRGO with changes in the particle size were characterized and discussed. After incorporation in low-density linear polyethylene (LLDPE) by melt blending, the composites have been characterized regarding their morphological, mechanical, and electrical properties to study the performance evolution of LLDPE/M-LTRGO with changing M-LTRGO size. The electrical properties of the LLDPE/M-LTRGO composites show the exact opposite trend with the M-LTRGO tablet, as the changing of the average M-LTRGO size. The opposite electrical phenomenon ascribes the small-size M-LTRGO resulting in a better dispersion in LLDPE matrix, which is determined by the mean surface-to-surface interparticle distance (IPD) from examination of scanning electron micrographs. |
Databáze: | OpenAIRE |
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