6β-Hydroxyrosenonolactone: a new metabolite from Trichothecium roseum link

Autor:	K. H. Overton, J. D. Connolly, A. J. Allison
Rok vydání:	1968
Předmět:	chemistry.chemical_classification Trichothecium roseum chemistry.chemical_compound chemistry biology Stereochemistry Metabolite Organic Chemistry Organic chemistry biology.organism_classification Lactone Rosenonolactone
Zdroj:	J. Chem. Soc. C. :2122-2125
ISSN:	0022-4952
DOI:	10.1039/j39680002122
Popis:	A new lactone, C20H28O4, m.p. 180–181°, [α]D–162°, isolated from the culture medium of Trichothecium roseum Link, has been identified as 6β-hydroxyrosenonolactone (1) by its chemical and spectroscopic properties and by its conversion into the diosphenol (6) also obtained from rosenonolactone. Lactone (1) is readily transformed into an isomer, formulated as (12), which has been isolated from the broth in a very minor amount.
Databáze:	OpenAIRE
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