Composition and electrocatalytic properties of the coatings formed by the ion-beam-assisted deposition of platinum from a pulsed arc-discharge plasma onto aluminum
Autor: | T. S. Mishchenko, V. G. Matys, V. V. Poplavskii |
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Rok vydání: | 2010 |
Předmět: | |
Zdroj: | Technical Physics. 55:296-302 |
ISSN: | 1090-6525 1063-7842 |
DOI: | 10.1134/s1063784210020222 |
Popis: | The structure, composition, and electrocatalytic properties of the coatings formed on aluminum by ion-beam-assisted deposition of platinum from the plasma of a pulsed arc discharge under conditions where deposited-metal ions are used as deposition-assisting ions are studied. The coating thickness reaches ~30 nm, and the near-surface content of platinum atoms in the coatings is ~2.6 × 1016 cm-2. The electrocatalytic activities of aluminum-based electrodes with the coatings in the reactions of electrochemical oxidation of methanol and ethanol, which form the basis for the principle of operation of low-temperature fuel cells (considered as promising chemical sources of an electric current), are significantly higher than the activity of a platinum electrode. |
Databáze: | OpenAIRE |
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