Crystal Structure and Luminescence of the [Dy(NO3)2(HMPA)4](NO3) Complex

Autor:	P. A. Zhikhareva, A. G. Mirochnik, B. V. Bukvetskii
Rok vydání:	2019
Předmět:	010302 applied physics Diffraction Materials science Coordination number Crystal structure 01 natural sciences Atomic and Molecular Physics and Optics Electronic Optical and Magnetic Materials 010309 optics Crystallography symbols.namesake Trigonal prism 0103 physical sciences symbols van der Waals force Luminescence
Zdroj:	Optics and Spectroscopy. 126:195-199
ISSN:	1562-6911 0030-400X
DOI:	10.1134/s0030400x19030044
Popis:	The crystal structure of the [Dy(NО3)2(HMPA)4](NО3) complex (HMPA is hexamethylphosphorotriamide) is studied by X-ray diffraction analysis. The crystals are constructed of two crystallographically independent complex cations [Dy(NО3)2(HMPA)4]+ and outer-sphere [NO3]−1 groups. The structure is represented by separate С24Н72DyN15O13P4 complexes bound by van der Waals interactions with pronounced layered morphology. The coordination polyhedron of Dy(III) with coordination number 8 is represented by a distorted trigonal prism with two centered square faces. The results of investigation of the luminescent properties in the visible and near-IR regions are presented.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a67704afd9c37de733763920ca1faca4 https://doi.org/10.1134/s0030400x19030044 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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