Flow Microreactor Synthesis of Fluorine-Containing Block Copolymers

Autor:	Jun-ichi Yoshida, Kana Akahori, Yusuke Takahashi, Aiichiro Nagaki
Rok vydání:	2014
Předmět:	Fluid Flow and Transfer Processes chemistry.chemical_classification Acrylate Chemistry Organic Chemistry Dispersity Methacrylate chemistry.chemical_compound Chemistry (miscellaneous) Polymer chemistry Copolymer Lithium chloride Microreactor Alkyl Living anionic polymerization
Zdroj:	Journal of Flow Chemistry. 4:168-172
ISSN:	2063-0212 2062-249X
DOI:	10.1556/jfc-d-14-00017
Popis:	Living anionic polymerization of perfluoroalkyl methacrylates initiated by 1,1-diphenylhexyllithium was conducted without adding lithium chloride in an integrated flow microreactor system. The high degree of polydispersity index (PID) control was achieved at 0°C (2-(nonafluorobutyl)ethyl and 2-(tridecafluorohexyl)ethyl methacrylates) or −40°C (2,2,2-trifluoroethyl methacrylate). The subsequent reaction of a reactive polymer chain end with alkyl methacrylates or tert-butyl acrylate led to the formation of fluorine-containing block copolymers with narrow PDI.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a674c13b3cbd623a7b3d8d50449131f8 https://doi.org/10.1556/jfc-d-14-00017 Zobrazit plný text záznamu Full text from SpringerLink