IR-Spektren15N-isotopenmarkierter Nitrido-, Chlorthionitreno- und Cyclothiazeno-Komplexe von Molybdän, Wolfram und Rhenium

Autor: Armin Dietrich, Kurt Dehnicke
Rok vydání: 2007
Předmět:
Zdroj: Zeitschrift für anorganische und allgemeine Chemie. 633:705-708
ISSN: 1521-3749
0044-2313
DOI: 10.1002/zaac.200600294
Popis: IR Spectra of 15N Labelled Nitrido, Chlorothionitreno and Cyclothiazeno Complexes of Molybdenum, Tungsten and Rhenium The IR spectra of selected, 15N labelled complexes of molybdenum, tungsten, and rhenium with metal-nitrogen multiple bonds are reported. The examined compounds include nitrido complexes (I), chlorothionitreno complexes (II), and cyclo-thiazeno complexes (III): The results of IR spectroscopy allow reliable assignments of characteristic vibrational modes for the types I and II, whereas the assignments of vibrational modes of compounds of type III are influenced by MN3S2 ring vibrations.
Databáze: OpenAIRE