IR-Spektren15N-isotopenmarkierter Nitrido-, Chlorthionitreno- und Cyclothiazeno-Komplexe von Molybdän, Wolfram und Rhenium
Autor: | Armin Dietrich, Kurt Dehnicke |
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Rok vydání: | 2007 |
Předmět: | |
Zdroj: | Zeitschrift für anorganische und allgemeine Chemie. 633:705-708 |
ISSN: | 1521-3749 0044-2313 |
DOI: | 10.1002/zaac.200600294 |
Popis: | IR Spectra of 15N Labelled Nitrido, Chlorothionitreno and Cyclothiazeno Complexes of Molybdenum, Tungsten and Rhenium The IR spectra of selected, 15N labelled complexes of molybdenum, tungsten, and rhenium with metal-nitrogen multiple bonds are reported. The examined compounds include nitrido complexes (I), chlorothionitreno complexes (II), and cyclo-thiazeno complexes (III): The results of IR spectroscopy allow reliable assignments of characteristic vibrational modes for the types I and II, whereas the assignments of vibrational modes of compounds of type III are influenced by MN3S2 ring vibrations. |
Databáze: | OpenAIRE |
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