Autor:	Dina V. Korchagina, L. E. Tatarova, Vladimir A. Barkhash
Rok vydání:	2002
Předmět:	chemistry.chemical_classification chemistry.chemical_compound chemistry Caryophyllene Organic Chemistry Acrolein Acetone Diastereomer Epoxide Organic chemistry Crotonaldehyde Aldehyde Isomerization
Zdroj:	Russian Journal of Organic Chemistry. 38:519-524
ISSN:	1070-4280
Popis:	Products of reaction between caryophyllene 4β,5α-epoxide and carbonyl compounds (acrolein, crotonaldehyde, α-methacrolein, and acetone) were synthesized on clay. Two diastereomers in reaction with each aldehyde and a single isomer with acetone were obtained. In reaction of the epoxide with acetone an isomerization product was isolated, 4,4,9-trimethyltricyclo[6.2.2.01,5]dodec-9-en-2β-ol that was unknown before.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a6726e8260603b5ea53dc7de42a77598 https://doi.org/10.1023/a:1016595005735 Zobrazit plný text záznamu Full text from SpringerLink