Elimination Reactions of Aryl Furylacetates Promoted by R2NH-R2NH2+in 70 mol% MeCN(aq). Effects of β-Aryl on the Ketene-Forming Transition-State

Autor: Bong Rae Cho, Ju Chang Kim, Sang Yong Pyun
Rok vydání: 2014
Předmět:
Zdroj: Bulletin of the Korean Chemical Society. 35:2143-2147
ISSN: 0253-2964
DOI: 10.5012/bkcs.2014.35.7.2143
Popis: the effect of the β-aryl group on the ketene-formingelimination was assessed.Key Words : Elimination, E2 and E1cb Mechanism, β–Aryl Group effectIntroductionExtensive studies of the structure-reactivity relationshipsin the ketene-forming elimination reactions have led to thequalitative understanding of the relationship between thereactant structure and the mechanism.
Databáze: OpenAIRE