Aqueous Phase Synthesis of (RCp)M(S2CNBz2)3(R=H,Me; M=Ti, Zr)

Autor:	He-Fu Guo, Shi-Wei Lu, Zhi-Qiang Wang
Rok vydání:	1991
Předmět:	Inorganic Chemistry Bipyramid Crystallography Zirconium Denticity Elemental analysis Chemistry Inorganic chemistry Acetyl acetone Aqueous two-phase system chemistry.chemical_element Physical and Theoretical Chemistry Titanium
Zdroj:	Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 21:1243-1247
ISSN:	1532-2440 0094-5714
DOI:	10.1080/15533179108020219
Popis:	The complexes (RCp)M(SaCNBza)8, where R=H, CH8;. M=Ti,Zr; Bz=CHaPh have been conveniently prepared by reaction of (RCp)2MCl2 with 3 eguiv. NaS2CNBz2 in the aqueous phase containing acetyl acetone. They have been characterized by elemental analysis, IR and 1H- NMR. IR studies demonstrated that the dithiocarhamate was bidentate- coordinated to titanium or zirconium. The pentagonal- bipyramidal structure of seven -coordinate complexes has been assigned.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a5f433a73b5ea726f9887c161f89bf52 https://doi.org/10.1080/15533179108020219 Zobrazit plný text záznamu