Thermal Isomerization of N-Bridged Cobalt Corrole Complexes through a Transiently Formed Axial Carbenoid

Autor:	Takashi Hayashi, Prosenjit Chattopadhyay, Takashi Matsuo, Jun Ohbayashi, Takanori Tsuji
Rok vydání:	2011
Předmět:	Organic Chemistry chemistry.chemical_element Photochemistry Inorganic Chemistry chemistry.chemical_compound Ethyl diazoacetate chemistry Polymer chemistry Proton NMR Moiety Physical and Theoretical Chemistry Corrole Carbenoid Cobalt Carbene Isomerization
Zdroj:	Organometallics. 30:1869-1873
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om101113x
Popis:	The reaction of cobalt(III) octaethylcorrole (CoOEC) with ethyl diazoacetate (EDA) under a nitrogen atmosphere led to the formation of bridged complexes with the carbene moiety inserted into one of the cobalt−nitrogen bonds. The bridged complexes underwent unique thermal isomerization, presumably via the transiently formed axial carbene complex. One of the thermodynamic isomers was characterized by 1H NMR and mass spectroscopic methods.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a5ce942e8a763aab76983f12f6ca37f7 https://doi.org/10.1021/om101113x Zobrazit plný text záznamu