Effect of the concentration of anion vacancies and the radius and charge on the cation of the stabilizing oxide on the conductivity of solid solutions based on ZrO2

Autor:	T. V. Chusovitina, S. Yu. Pliner, Yu. S. Toropov, D. S. Rutman
Rok vydání:	1985
Předmět:	Materials science Ionic radius Inorganic chemistry Oxide Electrolyte Conductivity chemistry.chemical_compound chemistry Chemical engineering Electrical resistivity and conductivity Ceramics and Composites Materials Chemistry Fast ion conductor Ionic conductivity Solid solution
Zdroj:	Refractories. 26:183-186
ISSN:	1573-9139 0034-3102
Popis:	The authors investigate the effect of the amount and form of stabilizing additives on the transport properties of solid electrolytes based on ZrO2. The powders were prepared from solid solutions by the process of the combined deposition of the components developed and the specimens were pressed from these powders under a pressure of 150 MPa then fired in a gas batch furnace at 1700 degrees C. The stabilization of ZrO2 by oxides with a larger cation radius leads to a reduction in the level of conductivity of the solid solutions. The use of a combined additive consisting of a mixture of rare-earth oxides to stabilize ZrO2 makes it possible to obtain solid electrolytes close in their electrophysical properties to the ZrO/sub 2/-Sc/sub 2/O/sub 3/ electrolytes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a5b84eecad0d12ce6237bb13d0884aa7 https://doi.org/10.1007/bf01387419 Zobrazit plný text záznamu Full text from SpringerLink